The Hollywood star and the Duchess, who have both worked to help victims of sexual abuse, met at Clarence House with Foreign Secretary William Hague.
The Oscar-winning actress is in London to co-chair the global summit to End Sexual Violence in Conflict with Mr Hague.
Speaking at the summit, Jolie said: “We are here for the nine-year-old girl in Uganda, kidnapped and forced into sexual slavery.
“We are here for the man in Bosnia, years after rape, still stigmatised, unable to earn enough money to buy bread for his family.
“We are here for all the forgotten, hidden survivors who have been made to feel ashamed or have been abandoned.
“And for the children of rape – we want the whole world to hear their stories and understand that this injustice cannot be tolerated, and that sorrow and compassion are not enough.”
Human rights lawyer and George Clooney’s, fiancee Amal Alamuddin also attended the event.
The Duchess and actress shake hands during their meeting at Clarence House.
The Duchess of Cornwall meets Angelina Jolie and Foreign Secretary William Hague.
The Hollywood star is in London to co-chair the global summit to End Sexual Violence in Conflict.
Jolie speaks at the Global Summit to End Sexual Violence in Conflict.
British Foreign Secretary William Hague with Angelina Jolie and Brad Pitt.
The Hollywood actress and Special Envoy of the United Nations High Commissioner for Refugees has devoted much of her time to helping victims of sexual abuse.
Angelina Jolie draws the outline of her hand to show support at the End Sexual Violence in Conflict summit.
Angelina Jolie and Brad Pitt join Film Director Zeresenay Berhane Mehari and Producer Dr Mehret Mandefro at the screening of ‘Difret’ at the Global Summit to End Sexual Violence in Conflict.
Amal Alamuddin attends the Global Summit to End Sexual Violence in Conflict.